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• W2093658705 abstract "A study of a new ferroelastic phase transition in Pb(Zr0.53Ti0.47)O3:Gd detected at 144 °C, induced by Gd doping is presented. The existence of such phase transition is barely detectable in the permittivity vs. temperature curve; however, it is made evident through the analyses of the temperature coefficient of the resonant frequency Tkf dependence with temperature in the radial mode resonance spectrum. This coefficient has a sharp discontinuity at around 144 °C. Micro Raman spectra show that the Raman modes associated to Pb/Gd and (Zr/Ti)O6 positioned at 93.6 cm−1 E(1TO) and 144 cm−1 E(1LO) have a minimum in intensity around 140 °C. Besides the modes of the tetragonal structure, there are the modes at 67.3 and 77.8 cm−1 corresponding to a rhombohedral structure, appearing at all temperatures. The Raman intensity vs. temperature plots of the different modes shows a minimum around 140 °C that confirms the ferroelastic transition detected in the resonance spectrum." @default.
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• W2093658705 date "2013-08-12" @default.
• W2093658705 modified "2023-10-03" @default.
• W2093658705 title "A ferroelastic phase transition in Pb(Zr0.53Ti0.47)O3:Gd" @default.
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• W2093658705 doi "https://doi.org/10.1063/1.4818334" @default.
• W2093658705 hasPublicationYear "2013" @default.
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