Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093663847> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2093663847 endingPage "9123" @default.
- W2093663847 startingPage "9119" @default.
- W2093663847 abstract "A synthesis of amphiphilic per(2,3-di-O-alkyl)-α- and β-cyclodextrins and hexakis(6-deoxy-6-thio-2,3-di-O-pentyl)-α-cyclodextrin and their monolayer behavior on a water surface is presented. Long alkyl chains were introduced by a treatment of the per(6-O-tert-butyldimethylsilyl) derivatives with an appropriate alkyl iodide in dimethylformamide in the presence of sodium hydride. A standard desilylation procedure followed by an iodination reaction afforded per(6-deoxy-6-iodo) analogues. In the latter reaction step, sulphur containing groups were introduced by nucleophilic substitution of the iodine with benzothiolate ion in dimethylformamide. The hexakis(6-deoxy-6-S-benzyl-2,3-di-O-pentyl)-α-cyclodextrin was transformed into extremely interesting hexakis(6-deoxy-6-thio-2,3-di-O-pentyl)-α-cyclodextrin. The surface pressure−mean molecular area (π−A) isotherms indicated that the synthesised amphiphilic cyclodextrin derivatives were capable of forming stable monolayers at the air–water interface. The shapes of the isotherms were typical for solid-like monolayers except for hexakis(6-deoxy-6-thio-2,3-di-O-pentyl)cyclomaltohexaoses which formed a more liquid monolayer." @default.
- W2093663847 created "2016-06-24" @default.
- W2093663847 creator A5007237452 @default.
- W2093663847 creator A5011254594 @default.
- W2093663847 creator A5013762531 @default.
- W2093663847 creator A5023090583 @default.
- W2093663847 creator A5058427616 @default.
- W2093663847 date "2000-11-01" @default.
- W2093663847 modified "2023-10-16" @default.
- W2093663847 title "Synthesis and monolayer behavior of amphiphilic per(2,3-di-O-alkyl)-α- and β-cyclodextrins and hexakis(6-deoxy-6-thio-2,3-di-O-pentyl)-α-cyclodextrin at an air–water interface" @default.
- W2093663847 cites W1967574967 @default.
- W2093663847 cites W1970083531 @default.
- W2093663847 cites W1970492433 @default.
- W2093663847 cites W2000032576 @default.
- W2093663847 cites W2000133010 @default.
- W2093663847 cites W2001128634 @default.
- W2093663847 cites W2019370936 @default.
- W2093663847 cites W2023827511 @default.
- W2093663847 cites W2031449004 @default.
- W2093663847 cites W2043290722 @default.
- W2093663847 cites W2069243732 @default.
- W2093663847 cites W2073675243 @default.
- W2093663847 cites W2085892380 @default.
- W2093663847 cites W2133896157 @default.
- W2093663847 cites W4235326200 @default.
- W2093663847 doi "https://doi.org/10.1016/s0040-4039(00)01628-2" @default.
- W2093663847 hasPublicationYear "2000" @default.
- W2093663847 type Work @default.
- W2093663847 sameAs 2093663847 @default.
- W2093663847 citedByCount "18" @default.
- W2093663847 countsByYear W20936638472012 @default.
- W2093663847 countsByYear W20936638472015 @default.
- W2093663847 countsByYear W20936638472018 @default.
- W2093663847 countsByYear W20936638472019 @default.
- W2093663847 countsByYear W20936638472021 @default.
- W2093663847 countsByYear W20936638472022 @default.
- W2093663847 countsByYear W20936638472023 @default.
- W2093663847 crossrefType "journal-article" @default.
- W2093663847 hasAuthorship W2093663847A5007237452 @default.
- W2093663847 hasAuthorship W2093663847A5011254594 @default.
- W2093663847 hasAuthorship W2093663847A5013762531 @default.
- W2093663847 hasAuthorship W2093663847A5023090583 @default.
- W2093663847 hasAuthorship W2093663847A5058427616 @default.
- W2093663847 hasConcept C155647269 @default.
- W2093663847 hasConcept C15920480 @default.
- W2093663847 hasConcept C178790620 @default.
- W2093663847 hasConcept C185592680 @default.
- W2093663847 hasConcept C188027245 @default.
- W2093663847 hasConcept C2776643749 @default.
- W2093663847 hasConcept C2777712214 @default.
- W2093663847 hasConcept C2778870691 @default.
- W2093663847 hasConcept C2779433975 @default.
- W2093663847 hasConcept C2780263894 @default.
- W2093663847 hasConcept C2780471494 @default.
- W2093663847 hasConcept C2781253882 @default.
- W2093663847 hasConcept C521977710 @default.
- W2093663847 hasConcept C55493867 @default.
- W2093663847 hasConcept C67407626 @default.
- W2093663847 hasConcept C7070889 @default.
- W2093663847 hasConceptScore W2093663847C155647269 @default.
- W2093663847 hasConceptScore W2093663847C15920480 @default.
- W2093663847 hasConceptScore W2093663847C178790620 @default.
- W2093663847 hasConceptScore W2093663847C185592680 @default.
- W2093663847 hasConceptScore W2093663847C188027245 @default.
- W2093663847 hasConceptScore W2093663847C2776643749 @default.
- W2093663847 hasConceptScore W2093663847C2777712214 @default.
- W2093663847 hasConceptScore W2093663847C2778870691 @default.
- W2093663847 hasConceptScore W2093663847C2779433975 @default.
- W2093663847 hasConceptScore W2093663847C2780263894 @default.
- W2093663847 hasConceptScore W2093663847C2780471494 @default.
- W2093663847 hasConceptScore W2093663847C2781253882 @default.
- W2093663847 hasConceptScore W2093663847C521977710 @default.
- W2093663847 hasConceptScore W2093663847C55493867 @default.
- W2093663847 hasConceptScore W2093663847C67407626 @default.
- W2093663847 hasConceptScore W2093663847C7070889 @default.
- W2093663847 hasIssue "47" @default.
- W2093663847 hasLocation W20936638471 @default.
- W2093663847 hasOpenAccess W2093663847 @default.
- W2093663847 hasPrimaryLocation W20936638471 @default.
- W2093663847 hasRelatedWork W1966147458 @default.
- W2093663847 hasRelatedWork W1992437527 @default.
- W2093663847 hasRelatedWork W1997462660 @default.
- W2093663847 hasRelatedWork W2008728427 @default.
- W2093663847 hasRelatedWork W2073675243 @default.
- W2093663847 hasRelatedWork W2321571631 @default.
- W2093663847 hasRelatedWork W2324898221 @default.
- W2093663847 hasRelatedWork W2346192045 @default.
- W2093663847 hasRelatedWork W2949751573 @default.
- W2093663847 hasRelatedWork W2486634905 @default.
- W2093663847 hasVolume "41" @default.
- W2093663847 isParatext "false" @default.
- W2093663847 isRetracted "false" @default.
- W2093663847 magId "2093663847" @default.
- W2093663847 workType "article" @default.