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- W2093668500 abstract "The cofactor forms of riboflavin (FMN and FAD) play a crucial role in the mediation of both enzymatic processes and light perception by photo-sensitive proteins, and thus structural analogues of this chromophore are highly useful tools to assist in the elucidation of enzymatic mechanisms. 1-Deazariboflavin has been rarely utilised for this purpose, due in part to its previously difficult and inefficient synthesis. Recent examination has enabled a remarkable improvement in the overall synthetic yield from 11.0 to 61.3%, allowing reliable production of 1-deazariboflavin for use as a tool in enzymatic mechanistic determination." @default.
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- W2093668500 date "2015-03-01" @default.
- W2093668500 modified "2023-10-14" @default.
- W2093668500 title "Rational improvement of the synthesis of 1-deazariboflavin" @default.
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- W2093668500 doi "https://doi.org/10.1016/j.tet.2015.01.053" @default.
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