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- W2093670689 abstract "We have made highly-conductive graphite fibres by pyrolysis or chemical vapour deposition (CVD) of cyanoacetylene on carbon fibres, followed by heat treatment. The spacing, d (002) of the graphite fibre is 3.356 Å, which corresponds to that of highly-oriented pyrolytic graphite (HOPG) from benzene. Measurements of Raman spectra, magnetoresistance and temperature dependence of conductivity show that cyanoacetylene forms highly-graphitezed fibre. Conductivity at room temperature is as high as 1.8 × 104 S/cm for the fibre heat treated at 3250°C. Intercalation of the fibre by fuming nutric acid increases the conductivity up to 1.3 × 105 S/cm in less than 10 min. The conductivity decreases slightly upon exposure of the nitrated fibre to air at ambient temperature. After this slight decrease, the conductivity is stable for at least 90 days." @default.
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- W2093670689 date "1986-01-01" @default.
- W2093670689 modified "2023-09-27" @default.
- W2093670689 title "Structure and conductivity of graphite fibres prepared by pyrolysis of cyanoacetylene" @default.
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- W2093670689 doi "https://doi.org/10.1016/0379-6779(86)90075-5" @default.
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