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- W2093672009 abstract "Lariat ethers with pendant amide groups have shown promise as new ion sensors because of their selectivity towards particular metal ions. In this study we report alkali and alkaline earth metal binding selectivities of dibenzo-16-crown-5 and fifteen dibenzo-16-crown-5 lariat ether amides (LEAs) as determined by electrospray ionization mass spectrometry (ESI-MS). Additionally, the influence of the acid/base nature of the solution on metal cation selectivity is investigated. The validity of using ESI-MS for determination of selectivities is established by analogous experiments using hosts with known binding constants for the same metal cations and solvent systems. Collisionally activated dissociation (CAD) is used to evaluate the influence of the alkali metal cation binding on the fragmentation of the LEAs." @default.
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- W2093672009 date "2003-11-01" @default.
- W2093672009 modified "2023-10-09" @default.
- W2093672009 title "Evaluation of alkali and alkaline earth metal cation selectivities of lariat ether amides by electrospray ionization mass spectrometry" @default.
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- W2093672009 doi "https://doi.org/10.1016/s1044-0305(03)00533-6" @default.
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