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• W2093674787 abstract "Nonlinear vibrational spectroscopy experiments examined solvent organization at the silica/binary solvent interface where the binary solvent consisted of methanol and acetonitrile in varying mole fractions. Data were compared with surface vibrational spectra acquired from silica surfaces exposed to a vapor phase saturated with the same binary solvent mixtures. Changes in vibrational band intensities suggest that methanol ideally adsorbs to the silica/vapor interface but acetonitrile accumulates in excess relative to vapor-phase composition. At the silica/liquid interface, acetonitrile's signal increases until a solution phase mole fraction of ∼0.85. At higher acetonitrile concentrations, acetonitrile's signal decreases dramatically until only a weak signature persists with the neat solvent. This behavior is ascribed to dipole-paired acetonitrile forming a bilayer with the first sublayer associating with surface silanol groups and a second sublayer consisting of weakly associating, antiparallel partners. On the basis of recent simulations, we propose that the second sublayer accumulates in excess." @default.
• W2093674787 created "2016-06-24" @default.
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• W2093674787 date "2014-07-25" @default.
• W2093674787 modified "2023-10-10" @default.
• W2093674787 title "Binary Solvent Organization at Silica/Liquid Interfaces: Preferential Ordering in Acetonitrile–Methanol Mixtures" @default.
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• W2093674787 doi "https://doi.org/10.1021/jz500906d" @default.
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