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• W2093678872 abstract "A relatively facile synthesis of the phosphine-arsine ligand, 2-diphenylarsinodiphenylphosphinoethane (pae) is described. This ligand forms low-spin square planar complexes [Ni(pae)2](ClO4)2 and [Ni(pae) X2] (X = Cl, Br, l, NCS), and the square pyramidal [Ni(pae)2Cl]BPh4. These complexes have been characterised by magnetic measurements and by electronic and infrared spectral measurements. A comparison of the electronic spectra of the planar [Ni(Ph2P⌢Y⌢ As Ph2)Cl2] (⌢ Y ⌢ = cis-vinyl, dimethylene, o-phenylene)indicates that a spectrochemical series, cis-CH CH>CH2CH2>oC6H4, exists. The occurrence of pentacoordinate nickel(II) with pae in the solid state, but not with the corresponding diphosphine ligand, 1,2-bisdiphenylphosphinoethane, is discussed." @default.
• W2093678872 created "2016-06-24" @default.
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• W2093678872 date "1975-01-01" @default.
• W2093678872 modified "2023-10-17" @default.
• W2093678872 title "Bidentate group VB chelates. Part X. An examination of the electronic spectra of some nickel(II) complexes of 2-diphenylarsinodiphenyl- phosphinoethane1−4" @default.
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• W2093678872 doi "https://doi.org/10.1016/s0020-1693(00)85713-8" @default.
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