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- W2093686143 abstract "Using a closed-bomb reaction calorimeter, the enthalpy of isomerization of quadricyclane (QC) to norbornadiene (NBD) in a benzene solution has been measured at room temperature in the presence of HgBr2. In the pure liquid states, a value of −89.03 ± 1.18 kJ mol−1 was obtained. From the enthalpies of vaporization of QC and NBD measured using a vaporization calorimeter (37.85 ± 0.04 and 34.83 ± 0.10 kJ mol−1, respectively), the gaseous enthalpy of isomerization was also derived as −92.05 ± 1.18 kJ mol−1." @default.
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- W2093686143 date "1993-06-01" @default.
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- W2093686143 title "Enthalpy of isomerization of quadricyclane to norbornadiene" @default.
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- W2093686143 doi "https://doi.org/10.1016/0040-6031(93)80451-f" @default.
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