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- W2093697249 abstract "Tetra-tert-butyldisilene and di-tert-butylsilylene, generated by photolysis of hexa-tert-butylcyclotrisilane (1), react with the triple bonds of hexa-2,4-diyne to provide the addition products octa-tert-butyl-2-methylene-5-methyl-3,4,7,8-tetrasilabicyclo[4.2.0]oct-1(6)-ene (5) and di-tert-butyl-2-methyl-3-propynylsilirene (6). Further treatment of 6 with 1 is thought to proceed via a bis(silirene) derivative to furnish the rearranged tetra-tert-butyl-3,6-dimethyl-2,5-disilabicyclo[2.2.0]hexa-1(6),3-diene (12). The structures of 5 and 12 were determined by X-ray crystallography." @default.
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- W2093697249 date "1998-02-24" @default.
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- W2093697249 title "Silylene and Disilene Additions to Hexa-2,4-diyne: Formation of a Propynylsilirene and of Bicyclic Compounds<sup>1</sup>" @default.
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- W2093697249 doi "https://doi.org/10.1021/om970791m" @default.
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