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- W2093702974 abstract "Under the conditions of in situ anomerisation, the 2-azido-4,6-di-O-benzoyl-2-deoxy-3-O-(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)-α-d-galactopyranosyl bromide reacted directly and with high selectivity with the reactive hydroxyl groups of l-serine and l-threonine derivatives to form α-glycosidically-linked products. Thus, the glycopeptides containing l-serine and l-threonine are more accessible. The disaccharide block could also be coupled with other reactive hydroxyl compounds to give compounds that contain the T-receptor. 2-Azido-4,6-di-O-benzoyl-2-desoxy-3-O-(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)-α-d-galactopyranosylbromid läßt sich unter den Bedingungen der in situ-Anomerisierungs-Reaktion direkt mit den reaktiven Hydroxylgruppen von l-Serin- und l-Threonin-Derivaten mit hoher Selektivität unter Bildung der α-glycosidisch verknüpften Produkte umsetzen. Auf diesem Wege sind die l-Serin- und l-Threonin-haltigen Glycopeptide besser zugänglich. Der Disaccharid-Syntheseblock ist zur Kupplung an reaktive Hydroxylgruppen anderer Produkte gleichfalls geeignet, um zu Substanzen zu gelangen, die die Determinante des T-Antigens enthalten." @default.
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- W2093702974 date "1984-12-01" @default.
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- W2093702974 title "Blocksynthese von O-glycopeptiden und anderen T-antigen strukturen" @default.
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- W2093702974 doi "https://doi.org/10.1016/0008-6215(84)85006-5" @default.
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