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- W2093711475 abstract "Halofluorination of norbornadiene with N-bromosuccinimide, N-chlorosuccinimide or xenon difluoride in the presence of polyhydrogen fluoride-pyridine resulted in the formation of three products: 3-endo-halo-5-exo-fluoro (2) and 3-exo-halo-5-exo-fluoronortricyclane (3), and 2-exo-fiuoro-7-syn-halo-norbornene-5 (4). The exo-attack of the electrophile on norbornadiene is slightly predominant (65% X = Br, 64% X = Cl, 73% X = F) over the endo-attack. The Meerwein-Wagner rearrangement occurred only in the case of chlorine or fluorine halosubstituents of β-carbonium ions formed by exo attack of the electrophile." @default.
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- W2093711475 date "1977-01-01" @default.
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- W2093711475 title "Halofluorination of norbornadiene. Evidence for endo and exo attack by electrophiles" @default.
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- W2093711475 doi "https://doi.org/10.1016/0040-4020(77)80144-0" @default.
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