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- W2093722342 abstract "Abstract The ν1 fundamental band of the ClO2 radical has been studied by means of the 10.6-μm CO2 and N2O laser Stark spectroscopy. More than 250 and 150 Stark resonances were assigned for the 35ClO2 and 37ClO2 species, respectively, and were analyzed together with the recent microwave and laser-microwave double resonance results to give molecular constants including spin-rotation interaction constants. The ν1 band origins and electric dipole moments both in the ground and ν1 states were determined accurately 35ClO2 37ClO2 ν 0 945.592 357(60) 939.602 909(66) cm−1 μ′ 1.788 39(13) 1.788 46(15) D μ″ 1.791 95(10) 1.792 10(13) D δμ −0.003 56(18) −0.003 64(26) D where standard deviations are given in parentheses. The molecular constants are consistent between the two isotopic species, and are also consistent with the results of the LMR and lasermicrowave double resonance experiments." @default.
- W2093722342 created "2016-06-24" @default.
- W2093722342 creator A5025184192 @default.
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- W2093722342 date "1983-04-01" @default.
- W2093722342 modified "2023-09-27" @default.
- W2093722342 title "CO2 and N2O laser Stark spectroscopy of the ν1 band of the ClO2 radical" @default.
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- W2093722342 doi "https://doi.org/10.1016/0022-2852(83)90253-9" @default.
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