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• W2093742303 abstract "The reduction potentials of the title compounds 4 have been measured by cyclic voltammetry. The effect of the substituents has been evaluated by using a linear free energy relationship treatment, thus evidencing that the present ortho-substituents affect the Epc values basically by electronic effects. A comparison with data previously collected on ortho-substituted (aryl)(2-nitrobenzo[b]thiophen-3-yl)amines 3 has provided some interesting information. Different electrochemical behaviors are observed during the reduction (a reversible process and an irreversible process are operating in 3 and 4, respectively): to elucidate the reasons for this different behavior, the “reversible” reduction potentials of 5 and of 6 have been measured. Moreover, higher susceptibility constants have been calculated for compounds of series 4 with respect to those of series 3 (ρ4 = 329 and ρ3 = 182, respectively). A rationale for all of these findings has been offered." @default.
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• W2093742303 date "2009-08-26" @default.
• W2093742303 modified "2023-09-23" @default.
• W2093742303 title "<i>ortho</i>-Substituted (Aryl)(3-nitrobenzo[<i>b</i>]thiophen-2-yl)amines: Study of the Electrochemical Behavior" @default.
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• W2093742303 doi "https://doi.org/10.1021/jp9056972" @default.
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