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- W2093742443 abstract "meta and para substituted benzalacetones lose the substituents after electron impact in a multi-step intramolecular aromatic substitution. The differences in the relative abundances of the benzopyrylium ions thus formed are not determined by the activation energies for the substituent losses but depend on a delicate balance between the thermodynamic stability of the intermediates involved and the rates of several H-shifts within the intermediates (kinetic stability). The consequences for the analytical utility of intramolecular aromatic substitution are discussed briefly." @default.
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- W2093742443 date "1981-09-01" @default.
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- W2093742443 title "Kinetic and thermodynamic effects on intramolecular aromatic substitution inmeta andpara substituted benzalacetones" @default.
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- W2093742443 doi "https://doi.org/10.1002/oms.1210160911" @default.
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