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• W2093753145 abstract "Abstract The β-diketone rare earth complex: Pr(HFA) 3 ·2H 2 O was synthesized and its amplitude and phase photoacoustic spectra in the range of 300–700 nm were reported. It was observed that the phase angle depends variously on the relaxation time τ and the optical absorption coefficient β with the incident light wavelength λ. A model of a homogeneous powder sample containing multiple optical absorption bands based on the Mandelis work was introduced to interpret the phase spectrum. It is shown that this model is very suitable for explaining the phase data associated with the π-π∗ transition and tf-tf transitions of the title complex. The phase angle ψ is mainly related to τ for the π-π∗ transition while it is determined by β for the tf-tf transition at relatively low chopping frequencies. Furthermore, the dependence of amplitude and phase information on the chopping frequency was also investigated." @default.
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• W2093753145 date "1996-06-01" @default.
• W2093753145 modified "2023-09-23" @default.
• W2093753145 title "Study on photoacoustic phase spectrum of rare earth complex: Pr(HFA)3·2H2O" @default.
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• W2093753145 doi "https://doi.org/10.1016/0584-8539(95)01593-0" @default.
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