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- W2093764508 abstract "The cation distribution in a polycrystalline sample of nominal composition “Tl0.5Pb0.5Sr2Ca2Cu3O9” with Tc = 118 K has been determined from resonant synchrotron X-ray diffraction data collected at the Cu K, Tl LIII, Pl LIII and Sr K edges. Cation disorder is found at all the non-copper sites according to the formula (Tl1−xPbx) (Sr2−yCay) (Ca2−zTlz)Cu3O9 where x = 0.53(2), y = 0.42(2) and z = 0.064(4) for our sample. The overall composition Tl0.53Pb0.53Sr1.58Ca2.36Cu3O9 confirms that an excess of Ca and a deficiency of Sr can stabilise the Tl, Pb-1223 structure." @default.
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- W2093764508 date "1994-03-01" @default.
- W2093764508 modified "2023-09-29" @default.
- W2093764508 title "Cation distribution in the superconducting Tl, Pb-1223 phase (“Tl0.5Pb0.5Sr2Ca2Cu3O9”) from resonant synchrotron powder X-ray diffraction" @default.
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- W2093764508 doi "https://doi.org/10.1016/0921-4534(94)90237-2" @default.
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