FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093792782> ?p ?o ?g. }

• W2093792782 endingPage "6518" @default.
• W2093792782 startingPage "6503" @default.
• W2093792782 abstract "The luminescence properties of thiocyanate and selenocyanate platinum(II) and palladium(II) complexes show strong variations with temperature and pressure. The d-d luminescence band maxima for [Pt(SCN)(4)](PPh(4))(2) (1), [Pt(SCN)(4)](n-Bu(4)N)(2) (2), and [Pt(SeCN)(4)](n-Bu(4)N)(2) (4) complexes are centered at ca. 14500 cm(-1) whereas those of the [Pd(SCN)(4)](n-Bu(4)N)(2) (3) and [Pd(SeCN)(4)](n-Bu(4)N)(2) (5) complexes are approximately 2000 cm(-1) lower in energy. Low-temperature luminescence spectra from single-crystal samples have broad bands with highly resolved vibronic structure indicating large displacements of the emitting-state potential energy minimum along several metal-ligand normal coordinates. The largest displacements involve the totally symmetric (a(1g)) stretching modes with frequencies of 295 cm(-1) (1), 303 cm(-1) (2), 274 cm(-1) (3), 195 cm(-1) (4), and 185 cm(-1) (5). The lower frequencies of these dominant progression-forming modes for the selenocyanate complexes lead to luminescence bands that are narrower by ca. 500 cm(-1) (fwhm) than those observed from the thiocyanate complexes. Under external pressures, the room-temperature luminescence intensities and lifetimes show considerable enhancement at pressures up to 40 kbar. This effect is largest for the palladium(II) complexes with lifetimes increasing from approximately 350 ns at ambient pressure up to 62 micros at 30 kbar, an increase by more than 2 orders of magnitude. The platinum(II) complexes exhibit a significant, but noticeably lesser increase of luminescence lifetimes and intensities with increasing pressure. The temperature- and pressure-dependent luminescence decay behavior is rationalized using the emitting-state molecular geometry determined from the resolved low-temperature luminescence spectra combined with the strong-coupling limit of radiationless decay theory." @default.
• W2093792782 created "2016-06-24" @default.
• W2093792782 creator A5001865981 @default.
• W2093792782 creator A5077288728 @default.
• W2093792782 creator A5083168740 @default.
• W2093792782 date "2003-09-06" @default.
• W2093792782 modified "2023-10-05" @default.
• W2093792782 title "Pressure-Induced Enhancements of Luminescence Intensities and Lifetimes Correlated with Emitting-State Distortions for Thiocyanate and Selenocyanate Complexes of Platinum(II) and Palladium(II)" @default.
• W2093792782 cites W13622562 @default.
• W2093792782 cites W1594314344 @default.
• W2093792782 cites W1618377049 @default.
• W2093792782 cites W1963919797 @default.
• W2093792782 cites W1967690979 @default.
• W2093792782 cites W1969749365 @default.
• W2093792782 cites W1969986021 @default.
• W2093792782 cites W1971070451 @default.
• W2093792782 cites W1971274408 @default.
• W2093792782 cites W1975659832 @default.
• W2093792782 cites W1978604564 @default.
• W2093792782 cites W1980323244 @default.
• W2093792782 cites W1989212977 @default.
• W2093792782 cites W1991491992 @default.
• W2093792782 cites W1992229928 @default.
• W2093792782 cites W1997778221 @default.
• W2093792782 cites W1999655015 @default.
• W2093792782 cites W2005184321 @default.
• W2093792782 cites W2005650147 @default.
• W2093792782 cites W2005877813 @default.
• W2093792782 cites W2007274640 @default.
• W2093792782 cites W2008232283 @default.
• W2093792782 cites W2008240823 @default.
• W2093792782 cites W2015029007 @default.
• W2093792782 cites W2033587456 @default.
• W2093792782 cites W2033704768 @default.
• W2093792782 cites W2033858152 @default.
• W2093792782 cites W2039376112 @default.
• W2093792782 cites W2039791068 @default.
• W2093792782 cites W2043257742 @default.
• W2093792782 cites W2043731106 @default.
• W2093792782 cites W2045241702 @default.
• W2093792782 cites W2046326025 @default.
• W2093792782 cites W2052528949 @default.
• W2093792782 cites W2053172655 @default.
• W2093792782 cites W2060676215 @default.
• W2093792782 cites W2061716734 @default.
• W2093792782 cites W2064550019 @default.
• W2093792782 cites W2066950818 @default.
• W2093792782 cites W2071788017 @default.
• W2093792782 cites W2072226786 @default.
• W2093792782 cites W2085229131 @default.
• W2093792782 cites W2085304716 @default.
• W2093792782 cites W2085637341 @default.
• W2093792782 cites W2085673845 @default.
• W2093792782 cites W2089657064 @default.
• W2093792782 cites W2089766741 @default.
• W2093792782 cites W2143753629 @default.
• W2093792782 cites W2152745328 @default.
• W2093792782 cites W2197441986 @default.
• W2093792782 cites W2264368894 @default.
• W2093792782 cites W2312745855 @default.
• W2093792782 cites W2952673899 @default.
• W2093792782 cites W2953298891 @default.
• W2093792782 cites W3024424600 @default.
• W2093792782 cites W3209316697 @default.
• W2093792782 cites W4232425373 @default.
• W2093792782 cites W4232980968 @default.
• W2093792782 cites W4245107742 @default.
• W2093792782 doi "https://doi.org/10.1021/ic0342503" @default.
• W2093792782 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14514328" @default.
• W2093792782 hasPublicationYear "2003" @default.
• W2093792782 type Work @default.
• W2093792782 sameAs 2093792782 @default.
• W2093792782 citedByCount "34" @default.
• W2093792782 countsByYear W20937927822012 @default.
• W2093792782 countsByYear W20937927822013 @default.
• W2093792782 countsByYear W20937927822014 @default.
• W2093792782 countsByYear W20937927822015 @default.
• W2093792782 countsByYear W20937927822016 @default.
• W2093792782 countsByYear W20937927822017 @default.
• W2093792782 countsByYear W20937927822018 @default.
• W2093792782 countsByYear W20937927822021 @default.
• W2093792782 crossrefType "journal-article" @default.
• W2093792782 hasAuthorship W2093792782A5001865981 @default.
• W2093792782 hasAuthorship W2093792782A5077288728 @default.
• W2093792782 hasAuthorship W2093792782A5083168740 @default.
• W2093792782 hasConcept C113196181 @default.
• W2093792782 hasConcept C116569031 @default.
• W2093792782 hasConcept C120665830 @default.
• W2093792782 hasConcept C121332964 @default.
• W2093792782 hasConcept C148869448 @default.
• W2093792782 hasConcept C161790260 @default.
• W2093792782 hasConcept C170493617 @default.
• W2093792782 hasConcept C179104552 @default.
• W2093792782 hasConcept C185592680 @default.
• W2093792782 hasConcept C2776294642 @default.
• W2093792782 hasConcept C43617362 @default.
• W2093792782 hasConcept C502130503 @default.
• W2093792782 hasConcept C518104683 @default.

• next