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- W2093802697 abstract "Binary diffusion coefficients D12 have been determined in supercritical chlorotrifluoromethane and in liquid as well as supercritical sulphurhexafluoride with supercritical fluid chromatography (SFC) using the peak broadening method. D12 values of benzene, methylbenzene, 1,4-dimethylbenzene, 1,3,5-trimethylbenzene, 1,3-dibromobenzene, 2-propanone and tetrachloromethane are reported at temperatures and pressures from 283 to 338 K and 3 to 15 MPa respectively; this corresponds to densities from 400 to 1000 kg m−3 for CClF3 and 300 to 1400 kg m−3 for SF6. The binary diffusion coefficients D12 are of the order of 10−8 m2 s−1. At constant temperature they exhibit a considerable dependence on density whereas the influence of temperature at constant density is relatively small." @default.
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- W2093802697 date "1987-01-01" @default.
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- W2093802697 title "Determination of binary diffusion coefficients in supercritical chlorotrifluoromethane and sulphurhexafluoride with supercritical fluid chromatography (SFC)" @default.
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