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- W2093814098 abstract "Thermodynamic analyses of different proposed reaction pathways to determine the thermodynamic feasibility of FT reactions on a mono- and diatomic Ru-complex as model catalysts were performed. Ru(CO)5 and Ru2(CO)9 were taken as starting complexes. The calculations illustrate that a minimum of two adjacent metal atoms is required for CO bond cleavage and chain growth in the Fischer–Tropsch synthesis. The CO-insertion mechanism seems to be thermodynamically most feasible reaction pathway on diatomic Ru-clusters." @default.
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- W2093814098 date "2008-06-01" @default.
- W2093814098 modified "2023-09-26" @default.
- W2093814098 title "Theoretical feasibility of CO-activation and Fischer–Tropsch chain growth on mono- and diatomic Ru complexes" @default.
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- W2093814098 doi "https://doi.org/10.1016/j.molcata.2008.03.023" @default.
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