Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093815467> ?p ?o ?g. }
- W2093815467 endingPage "7118" @default.
- W2093815467 startingPage "7110" @default.
- W2093815467 abstract "Vapor-phase adsorption and separation of the C8 alkylaromatic components p-xylene, m-xylene, o-xylene, and ethylbenzene on the metal-organic framework MIL-47 have been studied. Low coverage Henry adsorption constants and adsorption enthalpies were determined using the pulse chromatographic technique at temperatures between 230 and 290 degrees C. The four C8 alkylaromatic components have comparable Henry constants and adsorption enthalpies. Adsorption isotherms of the pure components were determined using the gravimetric technique at 70, 110, and 150 degrees C. The adsorption capacity and steepness of the isotherms differs among the components and are strongly temperature dependent. Breakthrough experiments with several binary mixtures were performed at 70-150 degrees C and varying total hydrocarbon pressure from 0.0004 to 0.05 bar. Separation of the different isomers could be achieved. In general, it was found that the adsorption selectivity increases with increasing partial pressure or degree of pore filling. The separation at a high degree of pore filling in the vapor phase is a result of differences in packing modes of the C8 alkylaromatic components in the pores of MIL-47." @default.
- W2093815467 created "2016-06-24" @default.
- W2093815467 creator A5011928943 @default.
- W2093815467 creator A5015838633 @default.
- W2093815467 creator A5019330175 @default.
- W2093815467 creator A5043025993 @default.
- W2093815467 creator A5053082566 @default.
- W2093815467 creator A5073012871 @default.
- W2093815467 creator A5077238999 @default.
- W2093815467 date "2008-05-10" @default.
- W2093815467 modified "2023-10-02" @default.
- W2093815467 title "Pore-Filling-Dependent Selectivity Effects in the Vapor-Phase Separation of Xylene Isomers on the Metal−Organic Framework MIL-47" @default.
- W2093815467 cites W1483072575 @default.
- W2093815467 cites W1971326664 @default.
- W2093815467 cites W1975982206 @default.
- W2093815467 cites W1981680521 @default.
- W2093815467 cites W1997531531 @default.
- W2093815467 cites W2005454218 @default.
- W2093815467 cites W2006819285 @default.
- W2093815467 cites W2010462271 @default.
- W2093815467 cites W2014909360 @default.
- W2093815467 cites W2027035049 @default.
- W2093815467 cites W2028679489 @default.
- W2093815467 cites W2036185390 @default.
- W2093815467 cites W2036676420 @default.
- W2093815467 cites W2051076532 @default.
- W2093815467 cites W2062755232 @default.
- W2093815467 cites W2068693583 @default.
- W2093815467 cites W2072417640 @default.
- W2093815467 cites W2075731109 @default.
- W2093815467 cites W2075883340 @default.
- W2093815467 cites W2075930557 @default.
- W2093815467 cites W2076775849 @default.
- W2093815467 cites W2083172037 @default.
- W2093815467 cites W2086560746 @default.
- W2093815467 cites W2093363291 @default.
- W2093815467 cites W2095414673 @default.
- W2093815467 cites W2096073539 @default.
- W2093815467 cites W2102348321 @default.
- W2093815467 cites W2115735355 @default.
- W2093815467 cites W2118298691 @default.
- W2093815467 cites W2120433419 @default.
- W2093815467 cites W2128141951 @default.
- W2093815467 cites W2138922861 @default.
- W2093815467 cites W2155423907 @default.
- W2093815467 cites W2164043498 @default.
- W2093815467 cites W2168288285 @default.
- W2093815467 cites W2170811673 @default.
- W2093815467 cites W254155216 @default.
- W2093815467 cites W4205476932 @default.
- W2093815467 cites W7049343 @default.
- W2093815467 doi "https://doi.org/10.1021/ja800686c" @default.
- W2093815467 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18470988" @default.
- W2093815467 hasPublicationYear "2008" @default.
- W2093815467 type Work @default.
- W2093815467 sameAs 2093815467 @default.
- W2093815467 citedByCount "267" @default.
- W2093815467 countsByYear W20938154672012 @default.
- W2093815467 countsByYear W20938154672013 @default.
- W2093815467 countsByYear W20938154672014 @default.
- W2093815467 countsByYear W20938154672015 @default.
- W2093815467 countsByYear W20938154672016 @default.
- W2093815467 countsByYear W20938154672017 @default.
- W2093815467 countsByYear W20938154672018 @default.
- W2093815467 countsByYear W20938154672019 @default.
- W2093815467 countsByYear W20938154672020 @default.
- W2093815467 countsByYear W20938154672021 @default.
- W2093815467 countsByYear W20938154672022 @default.
- W2093815467 countsByYear W20938154672023 @default.
- W2093815467 crossrefType "journal-article" @default.
- W2093815467 hasAuthorship W2093815467A5011928943 @default.
- W2093815467 hasAuthorship W2093815467A5015838633 @default.
- W2093815467 hasAuthorship W2093815467A5019330175 @default.
- W2093815467 hasAuthorship W2093815467A5043025993 @default.
- W2093815467 hasAuthorship W2093815467A5053082566 @default.
- W2093815467 hasAuthorship W2093815467A5073012871 @default.
- W2093815467 hasAuthorship W2093815467A5077238999 @default.
- W2093815467 hasBestOaLocation W20938154672 @default.
- W2093815467 hasConcept C113196181 @default.
- W2093815467 hasConcept C118792377 @default.
- W2093815467 hasConcept C121332964 @default.
- W2093815467 hasConcept C147789679 @default.
- W2093815467 hasConcept C150394285 @default.
- W2093815467 hasConcept C161790260 @default.
- W2093815467 hasConcept C178790620 @default.
- W2093815467 hasConcept C179366358 @default.
- W2093815467 hasConcept C185592680 @default.
- W2093815467 hasConcept C19184958 @default.
- W2093815467 hasConcept C2776396718 @default.
- W2093815467 hasConcept C2776692518 @default.
- W2093815467 hasConcept C2777207669 @default.
- W2093815467 hasConcept C2778142098 @default.
- W2093815467 hasConcept C2779533485 @default.
- W2093815467 hasConcept C2779896714 @default.
- W2093815467 hasConcept C43617362 @default.
- W2093815467 hasConcept C44280652 @default.
- W2093815467 hasConcept C96278889 @default.
- W2093815467 hasConcept C97355855 @default.