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- W2093815911 abstract "Abstract An efficient Ullmann‐type reductive homocoupling of aryl, vinyl and heteroaryl halides can be promoted by an aldehyde in tetraalkylammonium ionic liquids under very mild reaction conditions. This simple procedure generates symmetrical biaryls under relatively mild conditions. The ionic liquid is crucial for this process because it behaves simultaneously as a base, ligand and reaction medium. The role of the aldehyde is also discussed and a general mechanism for this unusual reaction is proposed. These results open the way to a new efficient method of Pd‐catalysed dehydrogenation of carbonyl compounds." @default.
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- W2093815911 date "2009-01-13" @default.
- W2093815911 modified "2023-10-18" @default.
- W2093815911 title "Palladium‐Nanoparticle‐Catalysed Ullmann Reactions in Ionic Liquids with Aldehydes as the Reductants: Scope and Mechanism" @default.
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- W2093815911 doi "https://doi.org/10.1002/chem.200801621" @default.
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