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- W2093839594 abstract "Irradiation of Cr(CO)3(η6-1,3,5-cycloheptatriene) (1) in the presence of bis(trimethylsilyl)ethyne results in [6 + 2] cycloaddition of the alkyne to the cycloheptatriene ligand, yielding Cr(CO)3(η4:2-7,8-bis(trimethylsilyl)bicyclo[4.2.1]nona-2,4,7-triene} (2, 60% yield, Φ=0.08), which upon oxidative decomposition with Ce(IV) releases the organic cycloadduct, 7,8-bis-(trimethylsilyl)bicyclo[4.2.1]-nona-2,4,7-triene (3). Photocatalytic hydrogenation of 1,3,5-cycloheptatriene in the presence of complex 1 affords 1,3-cycloheptadiene. This process involves 1,6-addition of hydrogen, as demonstrated by using D2." @default.
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- W2093839594 date "1991-12-01" @default.
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- W2093839594 title "Photoinduced Reactions of Cr(CO) <sub>3</sub> ‐Coordinated 1,3,5‐Cycloheptatriene: [6 + 2] Cycloaddition with an Alkyne and Catalytic 1,6‐Hydrogenation" @default.
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- W2093839594 doi "https://doi.org/10.1002/cber.19911241229" @default.
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