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- W2093896277 abstract "Emission and excitation spectra of 2- and 3-fluoropyridine (2- and 3-FP, respectively) vapors have been measured under the different conditions. It is shown that 3-FP vapor emits weak fluorescence from the S1(n, π∗) states. The fluorescence quantum yields are evaluated to be approximately 10−3 and 10−4 for 2- and 3-FP vapors, respectively, following the excitation into the S1 origin. The fluorescence yields decrease significantly with increasing excitation energy. The decrease of the yield is more significant for 2-FP than for 3-FP vapor. The data include vibrational analyses of the hot bands in the excitation spectra using the DFT calculation at the B3LYP/6-311++G∗∗ level." @default.
- W2093896277 created "2016-06-24" @default.
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- W2093896277 date "2010-05-01" @default.
- W2093896277 modified "2023-09-27" @default.
- W2093896277 title "Photophysics of 2- and 3-fluoropyridine vapors" @default.
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- W2093896277 doi "https://doi.org/10.1016/j.cplett.2010.03.064" @default.
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