Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093925723> ?p ?o ?g. }
Showing items 1 to 72 of
72
with 100 items per page.
- W2093925723 abstract "A facile chemo- and regioselective reactions of o-aminothiophenol (o-ATP) with itaconic anhydride is described. 1,5-Benzothiazepinyl-3-acetic acid is obtained in 81% yield via the exclusive Michael type addition of the thiol unit from o-ATP to the carbon-carbon double bond in itaconic anhydride followed by an intramolecular anhydride ring opening with an amine unit. The moderately stereoselective Michael type addition of the thiol unit from o-ATP to (-)-dimenthyl itaconate to obtain a mixture of diastereomers in a 7:3 ratio in 82% yield has been demonstrated. The reductive sulfur-sulfur bond cleavage in the dicarboxylic acid, 2-({2-[2-(3-carboxybut-3-enoylamino)phenyldisulfanyl]phenylcarbamoyl}methyl)acrylic acid, to the corresponding benzothiazolyl-2-methylacrylic acid in 84% yield, instead of the desired benzothio-azocine is also reported." @default.
- W2093925723 created "2016-06-24" @default.
- W2093925723 creator A5008393173 @default.
- W2093925723 creator A5012330159 @default.
- W2093925723 creator A5054766972 @default.
- W2093925723 creator A5063375677 @default.
- W2093925723 date "2007-02-01" @default.
- W2093925723 modified "2023-10-16" @default.
- W2093925723 title "Reactions of o-Aminothiophenol and o-Aminophenyl Disulfide with Itaconic Anhydride and (-)-Dimenthyl Itaconate: Access to Enantiomerically Pure 1,5-Benzothiazepines and Benzothiazolyl-2-methylacrylic Acid" @default.
- W2093925723 doi "https://doi.org/10.1055/s-2006-958977" @default.
- W2093925723 hasPublicationYear "2007" @default.
- W2093925723 type Work @default.
- W2093925723 sameAs 2093925723 @default.
- W2093925723 citedByCount "0" @default.
- W2093925723 crossrefType "journal-article" @default.
- W2093925723 hasAuthorship W2093925723A5008393173 @default.
- W2093925723 hasAuthorship W2093925723A5012330159 @default.
- W2093925723 hasAuthorship W2093925723A5054766972 @default.
- W2093925723 hasAuthorship W2093925723A5063375677 @default.
- W2093925723 hasConcept C134121241 @default.
- W2093925723 hasConcept C138716334 @default.
- W2093925723 hasConcept C155647269 @default.
- W2093925723 hasConcept C15920480 @default.
- W2093925723 hasConcept C161790260 @default.
- W2093925723 hasConcept C166595027 @default.
- W2093925723 hasConcept C178790620 @default.
- W2093925723 hasConcept C185592680 @default.
- W2093925723 hasConcept C188027245 @default.
- W2093925723 hasConcept C191897082 @default.
- W2093925723 hasConcept C192562407 @default.
- W2093925723 hasConcept C2779091418 @default.
- W2093925723 hasConcept C2779854550 @default.
- W2093925723 hasConcept C2779990784 @default.
- W2093925723 hasConcept C2781324293 @default.
- W2093925723 hasConcept C518881349 @default.
- W2093925723 hasConcept C521977710 @default.
- W2093925723 hasConcept C59759590 @default.
- W2093925723 hasConceptScore W2093925723C134121241 @default.
- W2093925723 hasConceptScore W2093925723C138716334 @default.
- W2093925723 hasConceptScore W2093925723C155647269 @default.
- W2093925723 hasConceptScore W2093925723C15920480 @default.
- W2093925723 hasConceptScore W2093925723C161790260 @default.
- W2093925723 hasConceptScore W2093925723C166595027 @default.
- W2093925723 hasConceptScore W2093925723C178790620 @default.
- W2093925723 hasConceptScore W2093925723C185592680 @default.
- W2093925723 hasConceptScore W2093925723C188027245 @default.
- W2093925723 hasConceptScore W2093925723C191897082 @default.
- W2093925723 hasConceptScore W2093925723C192562407 @default.
- W2093925723 hasConceptScore W2093925723C2779091418 @default.
- W2093925723 hasConceptScore W2093925723C2779854550 @default.
- W2093925723 hasConceptScore W2093925723C2779990784 @default.
- W2093925723 hasConceptScore W2093925723C2781324293 @default.
- W2093925723 hasConceptScore W2093925723C518881349 @default.
- W2093925723 hasConceptScore W2093925723C521977710 @default.
- W2093925723 hasConceptScore W2093925723C59759590 @default.
- W2093925723 hasLocation W20939257231 @default.
- W2093925723 hasOpenAccess W2093925723 @default.
- W2093925723 hasPrimaryLocation W20939257231 @default.
- W2093925723 hasRelatedWork W1530225585 @default.
- W2093925723 hasRelatedWork W1986904209 @default.
- W2093925723 hasRelatedWork W2058429927 @default.
- W2093925723 hasRelatedWork W2315847083 @default.
- W2093925723 hasRelatedWork W2395780673 @default.
- W2093925723 hasRelatedWork W2605021633 @default.
- W2093925723 hasRelatedWork W2949343656 @default.
- W2093925723 hasRelatedWork W2952737366 @default.
- W2093925723 hasRelatedWork W3043661862 @default.
- W2093925723 hasRelatedWork W4254790889 @default.
- W2093925723 isParatext "false" @default.
- W2093925723 isRetracted "false" @default.
- W2093925723 magId "2093925723" @default.
- W2093925723 workType "article" @default.