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- W2093944021 abstract "The major product from the reaction of the enoliminium ester [Me2CHC(OSO2CF3)NMe2]+ (5+) with [Mn(η4-C6H6)(CO)3]- (2-) is [Mn(CO)3{η5-C6H6C(iPr)NMe2}]+ (6+; X-ray), in which an iminium ion has been added to the reductively activated benzene ligand in 2-. Minor products include [{Mn(CO)3(η5-C6H6)-exo}2C(iPr)NHMe2]CF3SO3 (8(CF3SO3); X-ray) and [{Mn(CO)3(η5-C6H6)-exo}2C(iPr)NMe2] (7), with two Mn(CO)3 groups attached to the enoliminium ester derived backbone. The mechanistic relationship between the reactions that yield to formation of 6+, 8+, and 7 are unclear, since an increase in the ratio of 2- to 6+ does not increase the yield of 7, and reaction of 2- with the keteniminium salt prepared by reaction of 5+ with collidine leads directly to 6+. Hydrolysis of 6(PF6) generates [Mn(CO)3{η5-C6H6C(iPr)O}] (9), in which the benzene ligand in 2- has been acylated." @default.
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- W2093944021 date "2004-11-09" @default.
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- W2093944021 title "Vilsmeier−Haack−Arnold Acylation of the Reductively Activated Benzene Ligand in [Mn(CO)<sub>3</sub>(η<sup>4</sup>-C<sub>6</sub>H<sub>6</sub>)]<sup>-</sup>" @default.
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- W2093944021 doi "https://doi.org/10.1021/om040103g" @default.
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