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• W2093973709 abstract "Synthesis of a guest-free clathrate form of crystalline silicon was achieved by successive vacuum treatment and density separation of ${mathrm{Na}}_{x}{mathrm{Si}}_{136}$-based materials. The new allotrope of silicon has an open framework structure based upon slightly distorted tetrahedral atoms bound into five- and six-membered ring structures, and corresponds to a fully saturated and condensed fullerane-type solid. Theoretical calculations indicate that the new form of silicon should be a wide bandgap semiconductor. This prediction is borne out by experiment: electrical conductivity and optical absorption measurements yield a band gap of 1.9 eV, approximately twice the value of ``normal'' semiconducting silicon." @default.
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• W2093973709 date "2000-09-15" @default.
• W2093973709 modified "2023-10-18" @default.
• W2093973709 title "Low-density framework form of crystalline silicon with a wide optical band gap" @default.
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• W2093973709 doi "https://doi.org/10.1103/physrevb.62.r7707" @default.
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