FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2094006217> ?p ?o ?g. }

• W2094006217 endingPage "142" @default.
• W2094006217 startingPage "131" @default.
• W2094006217 abstract "We have discovered a spontaneous chiral ordering in thermotropic nematic liquid crystals forming hydrogen bonds, namely in trans -4-alkylcyclohexanecarboxylic acids, which do not contain any chiral group in the molecular structure, and have suggested a possible explanation of this phenomenon. The investigation was performed by polarizing light microscopy, using cells with glass substrates treated to give a uniform planar alignment in the nematic phase. On cooling from the isotropic phase, two types of nematic domains with different alignment were found to grow: some possessing a unidirectional planar orientation as expected, and others with a spontaneous twisted molecular arrangement. The appearance of the twisted domains and the sense of their twist were random, i.e. they always emerged in various regions of the cell with different twist sense: thus, they cannot be regarded as induced by stable defects in the surface aligning film. With the coalescence of the nematic droplets, the number of the domains with the spontaneous twist very quickly characterized by different handedness transformed into a racemic domain with uniform planar alignment. Here the explanation of the macroscopic texture is given in terms of molecular structure, based upon the ability of the carboxylic acids to organize through hydrogen bonds into not only dimers, but also trimers and oligomers. The microscopic structure influences the macroscopic twisted organization of the director inside the domains, and the surface lies normally to the helix axis. A brief review is given of work done in the fields of hydrogen bonded liquid crystals and of order transitions, together with a Landau-de Gennes model describing the mechanism of the spontaneous chiral ordering. decreased, since two chiral domains" @default.
• W2094006217 created "2016-06-24" @default.
• W2094006217 creator A5006849317 @default.
• W2094006217 creator A5035927694 @default.
• W2094006217 creator A5044995538 @default.
• W2094006217 date "1998-01-01" @default.
• W2094006217 modified "2023-09-25" @default.
• W2094006217 title "Spontaneous chiral domains in the nematic phase of achiral trans-4-alkylcyclohexanecarboxylic acids" @default.
• W2094006217 cites W1024815408 @default.
• W2094006217 cites W1668199367 @default.
• W2094006217 cites W1966158382 @default.
• W2094006217 cites W1968730768 @default.
• W2094006217 cites W1971976098 @default.
• W2094006217 cites W1973134108 @default.
• W2094006217 cites W1973538977 @default.
• W2094006217 cites W1977255443 @default.
• W2094006217 cites W1980856032 @default.
• W2094006217 cites W1984215592 @default.
• W2094006217 cites W1985969737 @default.
• W2094006217 cites W1988443411 @default.
• W2094006217 cites W2001087080 @default.
• W2094006217 cites W2009155194 @default.
• W2094006217 cites W2009735021 @default.
• W2094006217 cites W2016098407 @default.
• W2094006217 cites W2017941864 @default.
• W2094006217 cites W2020427649 @default.
• W2094006217 cites W2023458720 @default.
• W2094006217 cites W2027612317 @default.
• W2094006217 cites W2028116356 @default.
• W2094006217 cites W2030956031 @default.
• W2094006217 cites W2037560768 @default.
• W2094006217 cites W2038584694 @default.
• W2094006217 cites W2041560353 @default.
• W2094006217 cites W2044138380 @default.
• W2094006217 cites W2047074229 @default.
• W2094006217 cites W2053264075 @default.
• W2094006217 cites W2053672642 @default.
• W2094006217 cites W2054941917 @default.
• W2094006217 cites W2061861556 @default.
• W2094006217 cites W2063635703 @default.
• W2094006217 cites W2066469164 @default.
• W2094006217 cites W2068259737 @default.
• W2094006217 cites W2068429254 @default.
• W2094006217 cites W2070234395 @default.
• W2094006217 cites W2072708792 @default.
• W2094006217 cites W2074610005 @default.
• W2094006217 cites W2077517876 @default.
• W2094006217 cites W2082587860 @default.
• W2094006217 cites W2084479611 @default.
• W2094006217 cites W2087389684 @default.
• W2094006217 cites W2090607635 @default.
• W2094006217 cites W2110885949 @default.
• W2094006217 cites W2131815233 @default.
• W2094006217 cites W2166758162 @default.
• W2094006217 cites W2613356092 @default.
• W2094006217 cites W4234165472 @default.
• W2094006217 cites W4248642298 @default.
• W2094006217 doi "https://doi.org/10.1080/026782998207668" @default.
• W2094006217 hasPublicationYear "1998" @default.
• W2094006217 type Work @default.
• W2094006217 sameAs 2094006217 @default.
• W2094006217 citedByCount "30" @default.
• W2094006217 countsByYear W20940062172015 @default.
• W2094006217 countsByYear W20940062172016 @default.
• W2094006217 countsByYear W20940062172017 @default.
• W2094006217 countsByYear W20940062172018 @default.
• W2094006217 countsByYear W20940062172019 @default.
• W2094006217 countsByYear W20940062172022 @default.
• W2094006217 crossrefType "journal-article" @default.
• W2094006217 hasAuthorship W2094006217A5006849317 @default.
• W2094006217 hasAuthorship W2094006217A5035927694 @default.
• W2094006217 hasAuthorship W2094006217A5044995538 @default.
• W2094006217 hasConcept C112887158 @default.
• W2094006217 hasConcept C115961682 @default.
• W2094006217 hasConcept C121332964 @default.
• W2094006217 hasConcept C121684516 @default.
• W2094006217 hasConcept C13274807 @default.
• W2094006217 hasConcept C134786449 @default.
• W2094006217 hasConcept C149792144 @default.
• W2094006217 hasConcept C154945302 @default.
• W2094006217 hasConcept C159467904 @default.
• W2094006217 hasConcept C178790620 @default.
• W2094006217 hasConcept C185592680 @default.
• W2094006217 hasConcept C192562407 @default.
• W2094006217 hasConcept C22064058 @default.
• W2094006217 hasConcept C2524010 @default.
• W2094006217 hasConcept C26873012 @default.
• W2094006217 hasConcept C2776196297 @default.
• W2094006217 hasConcept C2781195486 @default.
• W2094006217 hasConcept C2994273327 @default.
• W2094006217 hasConcept C32909587 @default.
• W2094006217 hasConcept C33923547 @default.
• W2094006217 hasConcept C41008148 @default.
• W2094006217 hasConcept C44280652 @default.
• W2094006217 hasConcept C49040817 @default.
• W2094006217 hasConcept C8010536 @default.
• W2094006217 hasConcept C87355193 @default.
• W2094006217 hasConceptScore W2094006217C112887158 @default.

• next