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• W2094014303 abstract "The effects on the rate and activation parameters of a series of Menschutkin processes on changing from a molecular solvent to an ionic liquid were investigated. The removal of delocalised π-systems from the reagents does not affect the change in activation parameters on changing solvent. In each of the cases investigated, rate accelerations observed on moving to the ionic liquid could be attributed to an increase in reaction entropy. This suggests a specific interaction of the ionic liquid with the nucleophilic centre, rather than the delocalised π-systems of either the electrophile or the nucleophile." @default.
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• W2094014303 date "2012-01-01" @default.
• W2094014303 modified "2023-10-08" @default.
• W2094014303 title "Investigating the origin of entropy-derived rate accelerations in ionic liquids" @default.
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• W2094014303 doi "https://doi.org/10.1039/c1fd00060h" @default.
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