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- W2094020939 abstract "An aldol-type reaction of cyclic imines and cyclic lactims with carbonyl compounds activated by electron withdrawing trifluoromethyl or trichloromethyl groups proceeded without any catalyst under mild condition. β-Hydroxymethyl substituted cyclic imines or imidates are formed as a result of the reaction. The reduction of the prepared imines leads stereoselectively to the cyclic 1,3-aminoalcohols. Application of methyl trifluoropyruvate in this transformation opens an opportunity for the synthesis of γ-aminoacids derivatives which contain pyrrolidine moiety." @default.
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- W2094020939 date "2008-07-01" @default.
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- W2094020939 title "Diastereoselective synthesis of cyclic 1,3-aminoalcohols bearing CF3(CCl3)-groups" @default.
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- W2094020939 doi "https://doi.org/10.1016/j.jfluchem.2008.05.005" @default.
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