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- W2094039809 abstract "Abstract Solidification of eutectic melts in multiple oxide systems can produce directionally solidified eutectic composites by slow cooling, while rapid cooling would give the formation of amorphous phases as super cooled liquids. We have successfully fabricated an amorphous bulk ceramics in the ternary system HfO 2 –Al 2 O 3 –GdAlO 3 for the first time. It has the near eutectic composition of HfO 2 (14 mol%), Al 2 O 3 (63 mol%) and Gd 2 O 3 (23 mol%) and highly transparent, >85%, in the visible region after the cooling of around 200–500 K/s for 2–5 mm O globules. The sample had kept amorphous up to 1073 K but crystallized above 1273 K then lost the transparency. The formation of an amorphous phase could be discussed by the equilibrated temperature ( T 0 ) lines in meta-stable phase diagram. The present study suggests possible formation of transparent bulk ceramics by the melt-solidification of eutectic melts in various ternary or multiple phase systems." @default.
- W2094039809 created "2016-06-24" @default.
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- W2094039809 date "2006-01-01" @default.
- W2094039809 modified "2023-09-26" @default.
- W2094039809 title "Fabrication of transparent ceramics through melt solidification of near eutectic compositions in HfO2–Al2O3–GdAlO3 system" @default.
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- W2094039809 doi "https://doi.org/10.1016/j.jeurceramsoc.2005.09.002" @default.
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