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- W2094054475 abstract "The solvent parameter δs has been used for the first time to describe the solvent dependence of i.r. active stretching vibrations. A linear relationship between band frequency and δs was obtained for the ν(CO) bands of Mn2(CO)10 and Mn2(CO)8L2 (L = P(OPh)3 and PEt3) when measured in non-polar solvents. It has been shown, however, that polar solvents deviate from the line and that this deviation depends on the frequency of the stretching mode and type of mode involved. Deviations occur in both directions which is consistent with the first derivative of dipolar interactions (μ′) having either a positive or negative sign." @default.
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- W2094054475 date "1975-12-01" @default.
- W2094054475 modified "2023-09-27" @default.
- W2094054475 title "Use of the solvent parameter δs to describe the solvent dependence of the i.r. active carbonyl stretching vibrations of dimanganese decacarbonyl and some of its trans-disubstituted derivatives" @default.
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- W2094054475 doi "https://doi.org/10.1016/0584-8539(75)80233-9" @default.
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