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- W2094112228 abstract "A novel donor-acceptor polymer based on thiophene and isopyrazole has been prepared for use in n-doping applications. Nonpolymerizable monomer radical cations appear to be the predominant oxidation product, resulting in a need for extended cycling to produce adequate quantities of polymer for characterization. The electrochemical behavior of the polymer films produced is strongly dependent upon the conditions applied during electrodeposition and on the solvent used during cycling of the films. Cycling to reductive potentials during oxidative polymerization in acetonitrile was necessary to produce a polymer film capable of n-doping, likely resulting from a need to establish pathways for cation migration. The neutral polymer undergoes oxidation to the p-doped form at ca. vs in propylene carbonate and reduces back to neutral at ca. . Conversion of the neutral polymer to its n-doped form involves reductions at and , with reoxidation at and to return to the neutral form of the polymer." @default.
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- W2094112228 date "2007-01-01" @default.
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- W2094112228 title "Electrochemical Deposition of a New n-Doping Polymer Based on Bis(thienyl)isopyrazole" @default.
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- W2094112228 doi "https://doi.org/10.1149/1.2436991" @default.
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