Matches in SemOpenAlex for { <https://semopenalex.org/work/W2094132870> ?p ?o ?g. }
- W2094132870 endingPage "17211" @default.
- W2094132870 startingPage "17207" @default.
- W2094132870 abstract "Einstein and others derived the reciprocal dependence of the self-diffusivity D on the solute radius ru for large solutes based on kinetic theory. We examine here (a) the range of ru over which Stokes−Einstein (SE) dependence is valid and (b) the precise dependence for small solutes outside of the SE regime. We show through molecular dynamics simulations that there are two distinct regimes for smaller solutes: (i) the interaction or Levitation effect (LE) regime for solutes of intermediate size and (ii) the D ∝ 1/ru2 for still smaller solutes. We show that as the solute−solvent size ratio decreases, the breakdown in the Stokes−Einstein relationship leading to the LE regime has its origin in dispersion interaction between the solute and the solvent. These results explain reports of enhanced solute diffusion in solvents existing in the literature seen for small solutes for which no explanation exists." @default.
- W2094132870 created "2016-06-24" @default.
- W2094132870 creator A5052713514 @default.
- W2094132870 creator A5078247631 @default.
- W2094132870 date "2006-08-01" @default.
- W2094132870 modified "2023-10-17" @default.
- W2094132870 title "Breakdown of the Stokes−Einstein Relationship: Role of Interactions in the Size Dependence of Self-Diffusivity" @default.
- W2094132870 cites W1967210400 @default.
- W2094132870 cites W1971017062 @default.
- W2094132870 cites W1973146065 @default.
- W2094132870 cites W1974195642 @default.
- W2094132870 cites W1976610895 @default.
- W2094132870 cites W1976747623 @default.
- W2094132870 cites W1980355470 @default.
- W2094132870 cites W1980812765 @default.
- W2094132870 cites W1984038258 @default.
- W2094132870 cites W1984077735 @default.
- W2094132870 cites W1987081060 @default.
- W2094132870 cites W1995262263 @default.
- W2094132870 cites W2006661518 @default.
- W2094132870 cites W2011817436 @default.
- W2094132870 cites W2012611693 @default.
- W2094132870 cites W2014604623 @default.
- W2094132870 cites W2017037880 @default.
- W2094132870 cites W2017139461 @default.
- W2094132870 cites W2021131084 @default.
- W2094132870 cites W2025715214 @default.
- W2094132870 cites W2030765885 @default.
- W2094132870 cites W2034739109 @default.
- W2094132870 cites W2038874864 @default.
- W2094132870 cites W2047733492 @default.
- W2094132870 cites W2065401450 @default.
- W2094132870 cites W2067218823 @default.
- W2094132870 cites W2074685411 @default.
- W2094132870 cites W2076263163 @default.
- W2094132870 cites W2078146440 @default.
- W2094132870 cites W2078919646 @default.
- W2094132870 cites W2084557222 @default.
- W2094132870 cites W2088798892 @default.
- W2094132870 cites W2105674459 @default.
- W2094132870 cites W2119516638 @default.
- W2094132870 cites W2162488624 @default.
- W2094132870 cites W2314827379 @default.
- W2094132870 cites W2325672205 @default.
- W2094132870 cites W2417367996 @default.
- W2094132870 cites W36397967 @default.
- W2094132870 cites W4238964222 @default.
- W2094132870 doi "https://doi.org/10.1021/jp064364a" @default.
- W2094132870 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16928019" @default.
- W2094132870 hasPublicationYear "2006" @default.
- W2094132870 type Work @default.
- W2094132870 sameAs 2094132870 @default.
- W2094132870 citedByCount "38" @default.
- W2094132870 countsByYear W20941328702012 @default.
- W2094132870 countsByYear W20941328702013 @default.
- W2094132870 countsByYear W20941328702014 @default.
- W2094132870 countsByYear W20941328702015 @default.
- W2094132870 countsByYear W20941328702016 @default.
- W2094132870 countsByYear W20941328702017 @default.
- W2094132870 countsByYear W20941328702018 @default.
- W2094132870 countsByYear W20941328702019 @default.
- W2094132870 countsByYear W20941328702020 @default.
- W2094132870 countsByYear W20941328702021 @default.
- W2094132870 countsByYear W20941328702022 @default.
- W2094132870 countsByYear W20941328702023 @default.
- W2094132870 crossrefType "journal-article" @default.
- W2094132870 hasAuthorship W2094132870A5052713514 @default.
- W2094132870 hasAuthorship W2094132870A5078247631 @default.
- W2094132870 hasConcept C120665830 @default.
- W2094132870 hasConcept C121332964 @default.
- W2094132870 hasConcept C135889238 @default.
- W2094132870 hasConcept C136543978 @default.
- W2094132870 hasConcept C144133560 @default.
- W2094132870 hasConcept C146846114 @default.
- W2094132870 hasConcept C147597530 @default.
- W2094132870 hasConcept C159467904 @default.
- W2094132870 hasConcept C162853370 @default.
- W2094132870 hasConcept C177562468 @default.
- W2094132870 hasConcept C178635117 @default.
- W2094132870 hasConcept C178790620 @default.
- W2094132870 hasConcept C181199279 @default.
- W2094132870 hasConcept C185592680 @default.
- W2094132870 hasConcept C192239200 @default.
- W2094132870 hasConcept C193363816 @default.
- W2094132870 hasConcept C2775906791 @default.
- W2094132870 hasConcept C2780471494 @default.
- W2094132870 hasConcept C37668627 @default.
- W2094132870 hasConcept C38652104 @default.
- W2094132870 hasConcept C41008148 @default.
- W2094132870 hasConcept C55493867 @default.
- W2094132870 hasConcept C59593255 @default.
- W2094132870 hasConcept C69357855 @default.
- W2094132870 hasConcept C74650414 @default.
- W2094132870 hasConcept C97355855 @default.
- W2094132870 hasConcept C99987037 @default.
- W2094132870 hasConceptScore W2094132870C120665830 @default.
- W2094132870 hasConceptScore W2094132870C121332964 @default.
- W2094132870 hasConceptScore W2094132870C135889238 @default.