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- W2094134056 abstract "In a previous work [Nazarea, A. D. (1974)], a general expression was derived which yields an estimate of the intrinsic critical length when an oscillatory reactive mode couples to diffusional transport in reaction systems confined spatially such that translational diffusion can effectively be defined in terms of a principal axial co-ordinate. In this paper, it is shown how, under the assumption that the translational diffusion matrix is diagonal, this estimate can be applied to reactive processes in solutions in which an arbitrary number of inert components are present in addition to the buffered and unbuffered reactants. Hydrodynamic estimates of the intrinsic critical length, in terms of the period of the oscillatory reactive mode, of time-averaged viscosities and of equivalent Stokes radii, are obtained, making use of Kirkwood's theory of irreversible transport processes in solutions of large molecules. These estimates should be applicable to complex reaction systems of biological interest." @default.
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- W2094134056 date "1977-01-01" @default.
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- W2094134056 title "Intrinsic critical length associated with oscillatory reactive processes in complex solutions: Hydrodynamic estimates" @default.
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- W2094134056 doi "https://doi.org/10.1016/0022-5193(77)90359-9" @default.
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