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- W2094154909 abstract "Functionalized pyrrolic enols, 2-(2,2-dicyano-1-hydroxyethenyl)-1-methylpyrroles, synthesized from 2-ethenylpyrroles by a nucleophilic SEt-OH exchange, upon heating (75–142 °C) are readily rearranged to their 3-isomers in near to quantitative yield. The inter or intramolecular auto-protonation of a pyrrole ring by the acidic enol hydroxyl to form a mesomeric pyrrolium cation or zwitterion is suggested to be a key step in the rearrangement." @default.
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- W2094154909 date "2006-05-01" @default.
- W2094154909 modified "2023-10-14" @default.
- W2094154909 title "Easy α- to β-migration of an enol moiety on a pyrrole ring" @default.
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- W2094154909 doi "https://doi.org/10.1016/j.tetlet.2006.03.148" @default.
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