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- W2094164496 abstract "Details of the $K$ x-ray emission spectra of ${mathrm{K}}^{+}$ and ${mathrm{Cl}}^{ensuremath{-}}$ in KCl are discussed. It is shown that the valence hole is effectively localized to one atomic site during the lifetimes of both the potassium and chloride $1s$ holes. This localization is found to be an appreciable factor in the processes contributing to the emission. Calculations of the relative intensity of the cross-transition lines, of the type $1{{s}_{K}}^{ensuremath{-}1}ensuremath{rightarrow}3{{p}_{C1}}^{ensuremath{-}1}$, $K{ensuremath{beta}}_{5}$, are reported. The results of the calculations agree, to within 40%, with the observed values. The widths of the valence emission lines, due to the transitions $1{{s}_{K}}^{ensuremath{-}1}ensuremath{rightarrow}3{{p}_{C1}}^{ensuremath{-}1}$ and $1{{s}_{C1}}^{ensuremath{-}1}ensuremath{rightarrow}3{{p}_{C1}}^{ensuremath{-}1}$, $K{ensuremath{beta}}_{1,3}$ are considered. Because of the localization of the final hole state, both initial and final hole states of the $K{ensuremath{beta}}_{1,3}$ transition see the same crystal potential, and thus there is no first-order broadening due to spatial variation of that potential. This is not the case for the cross-transition line $K{ensuremath{beta}}_{5}$. A model due to Dexter is then used to show that the corrected width of the $K{ensuremath{beta}}_{5}$ line should be about 0.5 eV greater than that for $K{ensuremath{beta}}_{1,3}$. This corresponds to the observations made by Deslattes." @default.
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- W2094164496 date "1971-06-15" @default.
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- W2094164496 title "KX-Ray Emission from KCl" @default.
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- W2094164496 doi "https://doi.org/10.1103/physrevb.3.4377" @default.
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