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• W2094173854 abstract "The crystal chemistry of the cuprate apatitesAI4AII6(PO4)6CuxOy(H)z (A = Ca, Sr and Ba) was investigated by powder X-ray (PXRD) and neutron diffraction (PND) and X-ray photoelectron spectroscopy (XPS). The refined crystal structures confirmed earlier X-ray diffraction studies that showed copper resides in the apatite channels and additionally, located hydrogen. For all materials copper is primarily divalent (Cu2+) but in the calcium and strontium analogues co-exists with minor Cu3+. This is in contrast with a previous work where Cu1+ and Cu2+ were reported." @default.
• W2094173854 created "2016-06-24" @default.
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• W2094173854 date "2009-01-01" @default.
• W2094173854 modified "2023-10-15" @default.
• W2094173854 title "The crystal chemistry of the alkaline-earth apatites A10(PO4)6CuxOy(H)z (A = Ca, Sr and Ba)" @default.
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• W2094173854 doi "https://doi.org/10.1039/b906639j" @default.
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