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• W2094227545 abstract "Abstract The methods of isothermal and dynamic thermogravimetry have been used to study the degradation of poly(N-vinylcarbazole) (PNVC). The multiple heating rate method has been used, as a dynamic method, to obtain kinetic parameters. A linear relationship between the activation energy. E, and M w −1 ( M w being weight average molecular weight) was found. From isothermal experiments, a temperature was found for which E was independent of molecular weight. We could then refer to a degradation characteristic- temperature of the polymer. On the other hand, altering the heating rate leads to changes in the values of E for each molecular weight indicating two kinds of scission: one occurs in the backbone, producing mainly monomer; in the other, both side-group and backbone scissions occur producing different products." @default.
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• W2094227545 date "1982-01-01" @default.
• W2094227545 modified "2023-09-24" @default.
• W2094227545 title "The influence of molecular weight on the degradation of poly(N-vinylcarbazole)" @default.
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• W2094227545 doi "https://doi.org/10.1016/0014-3057(82)90087-8" @default.
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