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- W2094248924 abstract "The first dynamic kinetic asymmetric transformation of racemic biaryl substrates on the basis of axial-to-central chirality transfer has been realized. Chiral Pd-NHC complexes were found to catalyze the dynamic kinetic asymmetric spiroannulation of 4-(2-bromoaryl)-naphthalen-1-ols (or 2′-bromo-[1,1′-biphenyl]-4-ols) with internal alkynes, affording a series of enantioenriched spirocyclic products bearing an all-carbon quaternary stereocenter in good yields (up to 95%) with excellent enantioselectivities (up to 97% ee)." @default.
- W2094248924 created "2016-06-24" @default.
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- W2094248924 date "2015-04-10" @default.
- W2094248924 modified "2023-10-16" @default.
- W2094248924 title "Palladium-Catalyzed Dynamic Kinetic Asymmetric Transformation of Racemic Biaryls: Axial-to-Central Chirality Transfer" @default.
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- W2094248924 doi "https://doi.org/10.1021/jacs.5b01285" @default.
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