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- W2094281997 abstract "Abstract The irradiation of acetonitrile solutions of Fe(CNCH3)62+ in bands of the ligand field provoked consecutive reactions of photosubstitution CNCH3NCCH3. Two partial steps of the process were evidenced: at the beginning a monosolvated intermediate Fe(CNCH3)5(NCCH3)2+ (I) was formed; subsequently this latter in turn underwent photosolvation to Fe(CNCH3)4(NCCH3)22+ (II). Both the solvated intermediates were isolated and characterized. The quantum yields of the two consecutive processes were calculated; it was found that both the quantum yields decreased as the irradiation wavelenght increased. A general mechanism of photosolvation for isocyanides of FeII was proposed." @default.
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- W2094281997 date "1985-07-01" @default.
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- W2094281997 title "Photochemical and thermal behaviour of isocyanide complexes. IV. Photochemistry of Fe(CNCH3)6(BF4)2 in acetonitrile" @default.
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- W2094281997 doi "https://doi.org/10.1016/s0020-1693(00)85991-5" @default.
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