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- W2094304120 abstract "The integrated absorptions of the IR active bands at about 1390 cm−1, 1080 cm−1 and 780 cm−1 were used to determine the content of hexagonal boron nitride h-BN (sp2 bonding state) and cubic boron nitride c-BN (sp3 bonding state) modifications in r.f. sputtered stoichiometric BN films. For the calculation of oscillator number densities in hexagonal boron nitride (h-BN) from integrated absorptions, calibration constants Ah can be used, which are found to be 1.7 × 1019 cm−2 for the BN stretching vibration at 1390 cm−1 and 9.1 × 1019 cm−2 for the BNB bending vibration at 780 cm−1, respectively. It is shown that the ratio of the volume fractions ⨍c/⨍h of mixed h/c-BN films can be determined from the ratios of the absorption coefficients α(1080 cm−1)/α(1390 cm−1) and α(1080 cm−1)/α(780 cm−1) multiplied by factors of 0.6 and 0.19, respectively." @default.
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- W2094304120 date "1994-06-01" @default.
- W2094304120 modified "2023-09-26" @default.
- W2094304120 title "Infrared spectroscopic investigations on h-BN and mixed h/c-BN thin films" @default.
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- W2094304120 doi "https://doi.org/10.1016/0040-6090(94)90876-1" @default.
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