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- W2094304894 abstract "Ga3P3O12(OH), H3C-NH2-CH3 was obtained by hydrothermal synthesis (453 K, autogeneous pressure, 24 hr) from a mixture of Ga2O3, P2O5, HF, dimethylamine and H2O in the ratio 1:1:2:2:80. It is monoclinic (space group P 21/n (No. 14)) with a = 8.787(1) Å, b = 17.783(3) Å, c = 9.204(1) Å, β = 109.56(1)°, V = 1355.2(5) Å3, Z = 4. It belongs to the AlPO4-21 (or GaPO4-C4) structure type. The three-dimensional network is built up from corner-linked [Ga3(PO4)3(OH)] units composed of three PO4 tetrahedra, two trigonal bipyramids, and one tetrahedron of gallium. As previously described, the framework delimits three-, four-, five-, and eight-membered rings. The protonated amine is inserted in the eight-membered tunnels which are along [100] and [001]. The hydrogen bonding scheme is discussed." @default.
- W2094304894 created "2016-06-24" @default.
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- W2094304894 date "1994-08-01" @default.
- W2094304894 modified "2023-10-17" @default.
- W2094304894 title "Synthesis and X-Ray Structural Determination of a New Hydroxygallophosphate Ga3P3O12(OH), H3C-NH2-CH3 Isotypic with AlPO4-21" @default.
- W2094304894 doi "https://doi.org/10.1006/jssc.1994.1245" @default.
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