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- W2094308023 abstract "The i.r. spectra of monoisotopic CF379Br and of natural CF3Br have been investigated in the gas phase with a resolution of ∼ 0.04 cm−1. The rotational J structure of 2ν1, 2ν3, ν1 - ν3, ν1 + ν3, ν1 + ν2, ν2 + 2ν3 and 2ν2 + ν3 of CF379Br has been resolved, Furthermore vibrational transitions of hot bands and of further parallel bands have been measured. Numerous excited state molecular parameters ν0i, xij, αAi and αBi have been determined. Due to the accidental equivalence of ν1/2ν5 and ν2 + ν3, strong anharmonic resonance correlates all (n + 2)ν3/ν1 + (n - 1)ν3/2ν5(∥)+(n - 1)ν3/ν2 + nν3 levels." @default.
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- W2094308023 date "1982-01-01" @default.
- W2094308023 modified "2023-09-30" @default.
- W2094308023 title "Vibrational spectra and force constants of symmetric tops—XXIV. Vibrational and rotational analysis of parallel overtones and combination bands of CF3Br" @default.
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- W2094308023 doi "https://doi.org/10.1016/0584-8539(82)80082-2" @default.
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