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• W2094359611 abstract "Six new layered lanthanide molybdate and tungstate phases pillared by either naphthalenedisulfonate (NDS) or fumarate anions have been synthesized hydrothermally and structurally characterized. Five of these materials, [Nd(H2O)MoO4]2[2,6-NDS] (1), [Nd(H2O)MoO4]2[1,5-NDS] (2), [La(H2O)WO4]2[1,5-NDS] (3), [La(H2O)WO4]2[2,6-NDS] (4), and [Ce(H2O)MoO4]2[fumarate] (6), have a closely related cationic inorganic layer structure which comprises a bilayer of polyhedra leading to the formation of a framework layer containing small, inaccessible pores. These layers are pillared by the organic anions which also bridge between the lanthanide cations within the layers. In the La/WO4/2,6-NDS system, a second polymorph, [La2(H2O)2W2O8][2,6-NDS] (5), is observed. In this compound, the tungstate anions have dimerized, forming W2O84−. This dimer is unique and comprises two square-based pyramidal tungsten centers which are opposed to each other." @default.
• W2094359611 created "2016-06-24" @default.
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• W2094359611 date "2010-08-18" @default.
• W2094359611 modified "2023-10-18" @default.
• W2094359611 title "Synthesis and Structure of Pillared Molybdates and Tungstates with Framework Layers" @default.
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• W2094359611 doi "https://doi.org/10.1021/ic101145p" @default.
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• W2094359611 hasPublicationYear "2010" @default.
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