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- W2094366236 abstract "The application of two nitrogen ring expansion reactions to lasubine alkaloid synthesis is reported. The approach involves a conjugate reduction/alkylation sequence carried out on triisopropylsilyl-protected (S)-4-(−)-hydroxycyclopentenone, the formation of the quinolizidone ring system through nitrogen ring expansion, and the addition of an arylmetallic species to the resulting lactam. This work resulted in the preparation of 2-epi-lasubine II and a formal synthesis of lasubine II." @default.
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- W2094366236 date "2003-11-25" @default.
- W2094366236 modified "2023-10-15" @default.
- W2094366236 title "Ring Expansive Routes to Quinolizidine Alkaloids: Formal Synthesis of (−)-Lasubine II" @default.
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- W2094366236 doi "https://doi.org/10.1021/ol035965c" @default.
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