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- W2094374912 abstract "Unsaturated acyl CoA hydrase catalyzes the hydration of both trans- and cis-crotonyl CoA. The cis isomer is hydrated with 40% of the rate with which the trans isomer is hydrated. The product of hydration of trans-crotonyl CoA is l(+)β-hydroxylbutyryl CoA, while the product of hydration of cis-crotonyl CoA is d-(−)β-hydroxybutyrtl CoA. A mechanism is proposed for the reaction catalyzed by unsaturated acyl CoA hydrase. L'hydrase de lacyl CoA non saturé catalyse l'hydratation à la fois du trans-et du cis-crotonyl CoA. La vitesse d'hydratation de l'isomère cis est égale à 40% de celle de l'isomème trans. Le produit d'hydratation du trans-crotonyl CoA est le l(+)β-hydroxybutyryl CoA, tandis que le produit d'hydratation du cis-crotonyl CoA est le d(−)β-hydroxybutyryl CoA. Un mécanisme pour la réaction catalysée par l'hydrase de l'acyl CoA non saturé est proposé. Die Hydratase der ungesättigten Acylderivate des CoA katalysiert die Hydratation von cis- und trans-Crotonyl CoA. Die Hydratation der trans-Verbindung läuft mit 212 mal grösserer Geschwin-digkeit ab als die der cis-Verbindung. Das Produkt der Hydratation von trnns-Crotonyl CoA ist l(+)β-Oxybutyrul CoA und das Produkt der Hydradation von cis-Crotonyl CoA ist d(−)β-Oxybutyryl CoA. Ein Mechanismus für die Wirkungsweise der Hydratase wird vorgeschlagen." @default.
- W2094374912 created "2016-06-24" @default.
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- W2094374912 date "1956-01-01" @default.
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- W2094374912 title "Studies on the fatty acid oxidizing system of animal tissues IX. Stereospecificity of unsaturated acyl CoA hydrase" @default.
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- W2094374912 doi "https://doi.org/10.1016/0006-3002(56)90473-5" @default.
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