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- W2094386857 abstract "Abstract Modified titanate nanotubes with enhanced basicity were synthesized by the incipient wetness impregnation of sodium titanate nanotubes (Na-TNT) with basic cations (Mg 2+ , K + , Ba 2+ , Zn 2+ ). The essential morphology and mesoporosity of the nanotubes were maintained, as well as the tri-titanate structure, although in some cases (Mg 2+ ) ion exchange and intercalation reactions brought about some contraction of the rolled titanate layers. Basic sites were probed with CO 2 adsorption microcalorimetry and infrared spectroscopy, revealing strong ( Q ads > 150 kJ mol −1 ), medium (150 Q ads −1 ), and weak basic sites that were absent in Na-TNT. These sites could be identified correspondingly with IR bands for relevant carbonate and bicarbonate complexes. All modified TNT catalysts demonstrated high conversions for the COS and CS 2 hydrolysis reactions at 553 K, confirming the presence of important basic sites." @default.
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- W2094386857 date "2013-09-01" @default.
- W2094386857 modified "2023-10-13" @default.
- W2094386857 title "Titanate nanotubes as support of solid base catalyst" @default.
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- W2094386857 doi "https://doi.org/10.1016/j.tca.2013.01.005" @default.
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