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- W2094393840 abstract "It was found earlier in our laboratories that Ag ion-exchanged zeolite was capable of purifying 1-butene by selective adsorbing trace amounts of 1,3-butadiene. The effect of Ag content in Ag ion-exchanged Y-zeolite (Ag−Y) on 1,3-butadiene/1-butene adsorption was investigated using Ag−Y with different Si/Al ratios and different degrees of Ag+/Na+ exchange (AgNa−Y). AgNa−Y with a Ag content of 34 Ag/u.c. exhibited excellent adsorption performance in terms of both separation factor and uptake rate. The influence of H2S exposure on sorbent performance was also examined. Although both 1,3-butadiene and 1-butene adsorption amounts were decreased by H2S exposure, the separation factors remained well over 100, which were still good for purification. XPS analysis revealed that Ag+ in Ag−Y reacted with H2S to form Ag2S. The high selectivity for butadiene over 1-butene was indicative of the π-complexation ability of Ag2S. This work demonstrated that (1) an intermediate silver loading was the best for 1,3-butadiene/1..." @default.
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- W2094393840 date "2001-08-04" @default.
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- W2094393840 title "Influence of Ag Content and H<sub>2</sub>S Exposure on 1,3-Butadiene/1-Butene Adsorption by Ag Ion-Exchanged Y-Zeolites (Ag−Y)" @default.
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- W2094393840 doi "https://doi.org/10.1021/ie0102100" @default.
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