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• W2094394683 abstract "The magnetic susceptibility of liquid Rb – Au alloys and the optical absorption of the solid and liquid equimolar alloy RbAu have been measured up to temperatures of 1000°C. The optical gap of solid RbAu shows Urbach type behaviour with E0 = 2.75 ± 0.1 eV. On melting it is reduced by about 1 eV: Eg(510°C) = 1.35 ± 0.1 eV. The magnetic susceptibility exhibits a strong diamagnetic minimum near the equiatomic composition yielding further evidence that liquid RbAu is semiconducting and predominantly ionic in bonding. The observed deviation from the expected susceptibility value for purely ionic RbAu and the high optical absorption in the near infrared suggest that localized paramagnetic electron states exist in the ionic liquid, possibly in equilibrium with free carriers. Like Cs – Au the alkali metal-gold system Rb – Au thus closely resembles the alkali metal-halogen systems the major differences arising from the reduced charge transfer and chemical ordering in these alloys." @default.
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• W2094394683 date "1984-10-01" @default.
• W2094394683 modified "2023-09-25" @default.
• W2094394683 title "Magnetic Susceptibility and Optical Absorption Studies of Rb - Au Alloys" @default.
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• W2094394683 doi "https://doi.org/10.1002/bbpc.19840881007" @default.
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