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- W2094397878 abstract "Abstract The ferroelectric phase transition in deuterated benzil, C14H10O2, has been studied using capacitance measurements and neutron powder diffraction. Hydrogenous benzil shows a phase transition at 83.5 K from a high temperature P3121 phase to a cell-doubled P21 phase. The phase transition in d-benzil occurs at 88.1 K, a small isotope effect. Neutron powder diffraction was consistent with a low temperature phase of space group P21. Upon deuteration the transition remained first-order and the dynamics of the phenyl ring dominated the behaviour. The isotope effect can be attributed to the difference in mass and moment of inertia between C6H5 and C6D5." @default.
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- W2094397878 date "2005-12-01" @default.
- W2094397878 modified "2023-10-17" @default.
- W2094397878 title "Structural phase transition in d-benzil characterised by capacitance measurements and neutron powder diffraction" @default.
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- W2094397878 doi "https://doi.org/10.1016/j.ssc.2005.09.017" @default.
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